Publikation: Dissertationsschrift

Spectroscopic evidence for clusters of like-charged ions in ionic liquids

Grunddaten
Link
Abstract
Autoren
Einrichtung

Grunddaten

Titel	Spectroscopic evidence for clusters of like-charged ions in ionic liquids
Erscheinungsjahr	2017
Verlag	Universität Rostock
Verlagsort	Rostock
Publikationsform	Elektronische Ressource
Publikationsart	Dissertationsschrift
Sprache	Englisch
Letzte Änderung	18.04.2018 10:10:33
Bearbeitungsstatus	durch UB Rostock abschließend validiert
Dauerhafte URL	http://purl.uni-rostock.de/fodb/pub/56166
Links zu Katalogen

Abstract

In this work the counterintuitive phenomenon of attraction between ions of like charge is described for ionic liquids. It is based on cooperative hydrogen bonding leading to different sized cationic clusters. Experimentally these clusters are indicated by characteristic spectroscopic features like e.g. redshifts of OH vibrational frequencies. The experimental observables can be related to charge transfer and second order stabilization energy. Finally, a theoretical approach of stabilizing the cationic cluster network by either neutral molecules or negatively charged counterions has been done.

Autor

Strate, Anne

Externer Link

Beschreibung	Link
Link zur Online-Ressource (kostenfrei zugänglich ohne Registrierung)	http://rosdok.uni-rostock.de/resolve/urn/urn:nbn:de:gbv:28-diss2018-0055-3

Einrichtung

MNF/Institut für Chemie (IfCh)