Publikation: Dissertationsschrift

Exploration of transition-metal-catalyzed direct C-H arylation of nitro-substituted heteroarenes and further transformations of nitro group

Grunddaten
Abstract
Autoren
Einrichtung

Grunddaten

Titel	Exploration of transition-metal-catalyzed direct C-H arylation of nitro-substituted heteroarenes and further transformations of nitro group
Erscheinungsjahr	2015
Publikationsform	Elektronische Ressource
Publikationsart	Dissertationsschrift
Sprache	Englisch
Letzte Änderung	19.12.2015 03:19:21
Bearbeitungsstatus	durch UB Rostock abschließend validiert
Dauerhafte URL	http://purl.uni-rostock.de/fodb/pub/49967
Links zu Katalogen

Abstract

The present work aimed to study the transition-metal-catalyzed direct C-H arylation of various nitro-substituted heteroarenes, including 4-nitroimidazole derivatives, 4-nitropyrazole derivatives, fused 3-nitropyridines, nitro-substituted pyrrole and thiophene. Under optimized reaction conditions a wide range of coupling partners were perfectly tolerated. Additional empirical studies indicated that the nitro group has influence on the regioselectivity of the reactions. In addition, the multipurpose nature of nitro group as a versatile directing group was explored.

Autor

Gevorgyan, Ashot

Einrichtung

MNF/Institut für Chemie (IfCh)