Publikation: Dissertationsschrift

Synthesis and characterisation of cyclic polyphosphanes

Grunddaten
Link
Abstract
Autoren
Einrichtung

Grunddaten

Titel	Synthesis and characterisation of cyclic polyphosphanes
Erscheinungsjahr	2016
Verlag	Universität Rostock
Verlagsort	Rostock
Publikationsform	Elektronische Ressource
Publikationsart	Dissertationsschrift
Sprache	Englisch
Letzte Änderung	16.05.2019 12:28:07
Bearbeitungsstatus	durch UB Rostock abschließend validiert
Dauerhafte URL	http://purl.uni-rostock.de/fodb/pub/52584
Links zu Katalogen

Abstract

The synthesis and reactivity of the novel cyclotetraphosphane [ClP(-PMes*)]2 were studied. The cyclophosphane proved to be a versatile reagent in phosphorus chemistry, since its Cl-functionalised P4 backbone could be used as a building block in a variety of reactions with Lewis acids, bases as well as reducing agents. The rearrangement of P P bonds as well as a 1,2-Cl shift were identified as common reaction pathways to stabilise the products. All synthesised compounds were fully characterised, including experimental and theoretical methods.

Autor

Bresien, Jonas

Externer Link

Beschreibung	Link
Link zur Online-Ressource (kostenfrei zugänglich ohne Registrierung)	http://rosdok.uni-rostock.de/resolve/urn/urn:nbn:de:gbv:28-diss2016-0091-5

Einrichtung

MNF/Institut für Chemie (IfCh)