Publikation: Dissertationsschrift

Influence of the pore structure on the catalytic performance of Rh-supported Zr-MOFs in the hydroformylation of olefins

Grunddaten
Abstract
Autoren
Einrichtung

Grunddaten

Titel	Influence of the pore structure on the catalytic performance of Rh-supported Zr-MOFs in the hydroformylation of olefins
Erscheinungsjahr	2020
Verlagsort	Rostock
Seitenzahl	xiii, 94
Publikationsform	Druckschrift
Publikationsart	Dissertationsschrift
Sprache	Englisch
Letzte Änderung	18.03.2021 06:05:38
Bearbeitungsstatus	durch UB Rostock abschließend validiert
Dauerhafte URL	http://purl.uni-rostock.de/fodb/pub/65375
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Abstract

Zirconium-based metal-organic frameworks (Zr-MOFs) of different pore sizes and structure were synthesized and used for the preparation of the Rh-supported catalysts. The catalytic performance was studied in the hydroformylation of olefins to the corresponding aldehydes. A series of n-alk-1-enes of different chain length and bulky olefins with different size was used to study the influence of the pore size and structure. The results show that the Zr-MOF-based catalysts are very active and show high aldehyde selectivity.

Autor

Sun, Yanjun

Einrichtung

MNF/Institut für Chemie (IfCh)