Publikation: Dissertationsschrift

Hydrogen bond lifetimes and equilibria in hydroxyl-functionalized ionic liquids

Grunddaten
Abstract
Autoren
Einrichtung

Grunddaten

Titel	Hydrogen bond lifetimes and equilibria in hydroxyl-functionalized ionic liquids
Erscheinungsjahr	2021
Verlagsort	Rostock
Seitenzahl	258
Publikationsform	Druckschrift
Publikationsart	Dissertationsschrift
Sprache	Englisch
Letzte Änderung	12.01.2022 06:02:06
Bearbeitungsstatus	durch UB Rostock abschließend validiert
Dauerhafte URL	http://purl.uni-rostock.de/fodb/pub/67129
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Abstract

This work investigates the hydrogen bond (HB) lifetimes and equilibrium in hydroxyl-functionalized pyridinium-based ionic liquids. Two types of intermolecular HBs are observed: typical cation-anion HBs are competing with atypical cation-cation HBs . By employing molecular dynamics simulations, the equilibrium between those HBs was examined as a function of temperature and alkyl chain length. In addition, the influence of the different HBs on the structure and dynamics of the ionic liquid are discussed. Also, HB lifetimes where examined.

Autor

Neumann, Jan

Einrichtung

MNF/Institut für Chemie (IfCh)