Publikation: Dissertationsschrift

Synthesis and characterization of reactive pnictogen species for small-molecule activation

Grunddaten
Abstract
Autoren

Grunddaten

Titel	Synthesis and characterization of reactive pnictogen species for small-molecule activation
Erscheinungsjahr	2021
Verlagsort	Rostock
Seitenzahl	iv, 113
Publikationsform	Druckschrift
Publikationsart	Dissertationsschrift
Sprache	Englisch
Letzte Änderung	24.03.2022 06:02:41
Bearbeitungsstatus	durch UB Rostock abschließend validiert
Dauerhafte URL	http://purl.uni-rostock.de/fodb/pub/67877
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Abstract

This dissertation reports on the synthesis of novel pnictogen-based biradicals, diphosphanes and phosphaarsanes as sterically stabilized reactive main group compounds. The reactivity of the synthesized species toward small molecules was studied in detail. New bonding motifs such as phosphane arsanyldithiocarboxylates could be isolated. Furthermore, the reduction of a phosphanyl thioketone resulted in the formation of a rare, stable thioketyl radical. The species described in this work were characterized by experimental and theoretical methods.

Autor

Szych, Lilian