Publikation: Dissertationsschrift

Hydrogen bonding in mixtures of protic ionic liquids

Grunddaten
Abstract
Autoren
Einrichtung

Grunddaten

Titel	Hydrogen bonding in mixtures of protic ionic liquids
Untertitel	influence on structure and thermodynamic properties
Erscheinungsjahr	2022
Verlag	Universität Rostock
Verlagsort	Rostock
Seitenzahl	189
Publikationsform	Druckschrift
Publikationsart	Dissertationsschrift
Sprache	Englisch
Letzte Änderung	21.03.2024 06:02:04
Bearbeitungsstatus	durch UB Rostock abschließend validiert
Dauerhafte URL	http://purl.uni-rostock.de/fodb/pub/69978
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Abstract

In this work, the influence of hydrogen bonds on structure and thermodynamic properties of binary mixtures of protic ionic liquids (PILs), sharing the same cation, are investigated with molecular dynamics simulation. The observed non-ideal mixing behavior can be explained with the formation of complex hydrogen-bonded clusters. With the help of a newly developed simple lattice model the clusters can be described. Furthermore, the model shows that the mixing process is enthalpy-driven, not entropy-driven as one would expect.

Autor

Golub, Benjamin

Einrichtung

MNF/Institut für Chemie (IfCh)