Publikation: Dissertationsschrift

Hydrogen generation from renewable resources

Grunddaten
Abstract
Autoren

Grunddaten

Titel	Hydrogen generation from renewable resources
Erscheinungsjahr	2009
Publikationsform	Elektronische Ressource
Publikationsart	Dissertationsschrift
Sprache	Englisch
Letzte Änderung	19.03.2013 10:51:13
Bearbeitungsstatus	durch UB Rostock abschließend validiert
Dauerhafte URL	http://purl.uni-rostock.de/fodb/pub/32125
Links zu Katalogen

Abstract

Hydrogen generation from 2-propanol and formic acid and its direct use in fuel cells was studied. 2-propanol was dehydrogenated with ruthenium diamine catalysts. Formic acid was decomposed selectively to hydrogen and carbon dioxide in a system containing ruthenium catalysts and formic acid amine adducts. The best catalyst activity and productivity were achieved with in situ generated ruthenium phosphine catalysts, e.g. [RuCl2(benzene)]2 / dppe (TOF = 900 h-1, TON = 260.000). The influence of irradiation with visible light has been described for the ruthenium phosphine catalysts.

Autor

Loges, Björn