Publikation: Dissertationsschrift

Development of new homogeneous (enantioselective) hydrogenation catalysts based on bio-relevant metals

Grunddaten
Links
Abstract
Autoren

Grunddaten

Titel	Development of new homogeneous (enantioselective) hydrogenation catalysts based on bio-relevant metals
Erscheinungsjahr	2011
Publikationsform	Elektronische Ressource
Publikationsart	Dissertationsschrift
Sprache	Englisch
Letzte Änderung	19.03.2013 10:59:38
Bearbeitungsstatus	durch UB Rostock abschließend validiert
Dauerhafte URL	http://purl.uni-rostock.de/fodb/pub/34112
Links zu Katalogen

Abstract

This thesis presents the study and development of new catalysts based on first row transition metals for the (asymmetric) reduction of different C=O and C=N bonds. An iron cluster catalyst with a chiral tetradentate P2N2 ligand was discovered to catalyze the asymmetric transfer hydrogenation of N-diphenylphosphinylketimines. Subsequently the combination of a chiral Brønsted acid with a well-defined Shvo type iron complex creates an active catalyst which could hydrogenate a variety of N-aryl ketimines to amines using molecular hydrogen. Finally, an iron cluster catalyst was discovered to catalyze the reduction of amides with inexpensive PMHS.

Autor

Zhou, Shaolin

Externe Links

Beschreibung	Link
Metadaten	http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2011-0127-7
Volltext (kostenfrei zugänglich ohne Registrierung)	http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2011-0127-7&pdf
Link zur Online-Ressource	http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2011-0127-7