Publikation: Dissertationsschrift

Application of novel phosphine ligands in palladium-catalyzed cross-coupling reactions

Grunddaten
Links
Abstract
Autoren

Grunddaten

Titel	Application of novel phosphine ligands in palladium-catalyzed cross-coupling reactions
Erscheinungsjahr	2009
Publikationsform	Elektronische Ressource
Publikationsart	Dissertationsschrift
Sprache	Englisch
Letzte Änderung	19.03.2013 10:50:06
Bearbeitungsstatus	durch UB Rostock abschließend validiert
Dauerhafte URL	http://purl.uni-rostock.de/fodb/pub/38054
Links zu Katalogen

Abstract

This thesis describes the application of 2-phosphino-N-aryl-heterocycles as ligands in Pd-catalyzed CC, CN and CO bond forming reactions. Based on prior studies, 2-phosphino-N-arylindoles and -pyrrols were found to form efficient catalysts with Pd-salts in the Sonogashira coupling of (hetero)aryl bromides and the Pd-catalyzed monoarylation of ammonia. The novel imidazole-based phosphines were prepared after a modular synthesis and are stable towards air. They were employed in the Pd-catalyzed phenol synthesis, the Heck-Cassar coupling, and the Pd-catalyzed monoarylation of ammonia. Furthermore, mechanistic studies in the Pd-catalyzed hydroxylation were undertaken.

Autor

Torborg, Christian

Externe Links

Beschreibung	Link
Metadaten	http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2009-0174-3
Volltext (kostenfrei zugänglich ohne Registrierung)	http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2009-0174-3&pdf
Link zur Online-Ressource	http://rosdok.uni-rostock.de/file/rosdok_derivate_000000004073/Dissertation_Torborg_2009.pdf
Link zur Online-Ressource	http://d-nb.info/999072188/34
Link zur Online-Ressource	http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2009-0174-3