Publikation: Dissertationsschrift

Synthesis of 1-alkenylpyrenes and of fluorinated arenes by palladium(0)-catalyzed cross-coupling reactions and photophysical properties of the products

Grunddaten
Abstract
Autoren
Einrichtung

Grunddaten

Titel	Synthesis of 1-alkenylpyrenes and of fluorinated arenes by palladium(0)-catalyzed cross-coupling reactions and photophysical properties of the products
Erscheinungsjahr	2011
Publikationsform	Elektronische Ressource
Publikationsart	Dissertationsschrift
Sprache	Englisch
Letzte Änderung	19.03.2013 10:59:30
Bearbeitungsstatus	durch UB Rostock abschließend validiert
Dauerhafte URL	http://purl.uni-rostock.de/fodb/pub/39891
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Abstract

The palladium(0)-catalyzed Heck cross coupling reactions of 1-bromopyrene provided functionalized alkenylpyrenes with styrenes and acrylates by single fold Heck reactions. Suzuki-Miyaura cross coupling reactions of the differently substituted di and mono fluoro benzenes with different arylboronic acids afforded fluoro-substituted terphenyls with excellent site-selectivity. Sonogashira and Suzuki-Miyaura coupling reactions of 1,2-difluoro, 1,3-difluoro, 1,4-difluoro, 1-fluoro, tetraiodobenzenes and pentaiodobenzenes respectively provided tetra- and penta-alkynylated and arylbenzene products.

Autor

Sharif Akbar, Muhammad

Einrichtung

MNF/Institut für Chemie (IfCh)