Publikation: Dissertationsschrift

Synthesis of highly functionalized carbacycles, heterocycles and silylium-arene adducts by cyclocondensations, palladium catalyzed cross-coupling reactions and activation by [Me3Si]+ cation

Grunddaten
Links
Abstract
Autoren
Einrichtung

Grunddaten

Titel	Synthesis of highly functionalized carbacycles, heterocycles and silylium-arene adducts by cyclocondensations, palladium catalyzed cross-coupling reactions and activation by [Me3Si]+ cation
Erscheinungsjahr	2012
Publikationsform	Elektronische Ressource
Publikationsart	Dissertationsschrift
Sprache	Englisch
Letzte Änderung	03.04.2013 02:12:19
Bearbeitungsstatus	durch UB Rostock abschließend validiert
Dauerhafte URL	http://purl.uni-rostock.de/fodb/pub/41291
Links zu Katalogen

Abstract

The Me3SiOTf-mediated condensation of 1-ethoxy-2-fluoro-1,3-bis trimethylsilyloxy) 1,3-dienes with 3-cyanochromones afforded fluorinated azaxanthones or biaryls. The [4+2] cycloaddition of 1-ethoxy-2-fluoro-1,3-bis(trimethylsilyloxy)-1,3-diene with DMAD afforded dimethyl 4-fluoro-3,5-dihydroxyphthalate. Various arylated phthalates, naphthoates, indoles, are synthesized Pd(0)-catalyzed Suzuki cross-coupling reaction and studied. The experimental and theoretical study of the silylium arene adducts ([Me3Si-Ar][B(C6F5)4]) and the catalytic trimerisation of bissilylated diazomethane are studied.

Autor

Ibad, Muhammad Farooq

Externe Links

Beschreibung	Link
Metadaten	http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2013-0037-7
Volltext (kostenfrei zugänglich ohne Registrierung)	http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2013-0037-7&pdf
Link zur Online-Ressource	http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2013-0037-7

Einrichtung

MNF/Institut für Chemie (IfCh)